Buffers

Buffer Q&A:

Why do we care about buffers?

  • It will keep pH constant upon adding acid or base

What do we need in a buffer?

  •  a weak acid ($HA$) and its conjugate base ($A^-$)
    • if we add a base, it will react with the acid
    • if we add an acid, it will react with the base

You might ask, “can any buffer work?”

  • the desired pH is +/-1 from the buffer $pK_a$

When is a buffer no longer a buffer?

  • When you use up one entire speicies

What unit should I work in when I am using buffers?

  • MOLES

Things to consider when making a buffer:

  • pH +/- 1 from $pK_a$
  • What materials you have available (you can make a buffer multiple ways)
    • option 1: 2 solids ($[HA]$ and $[A^-]$)
    • option 2: 1 solid and 1 solution ($[HA]$ solid & $[A^-]$ solution)
    • option 3: 1 solid and 1 solution ($[HA]$ solution & $[A^-]$ solid)
  • use Henderson Hasslebach Equation (in pH & pOH)