Colligative Properties

Properties of your substance will differ depending on whether your substance is a pure solute or solvent. Having impurities will change the properties of the substance you are studying.


Types of colligative properties:

  • vapor pressure lowering: once you dissolve a nonvolatile substance in volatile liquid, the vapor pressure will lower
  • boiling point elevation: $\Delta T_b = K_b mi$
    • $K_b$: boiling point elevation constant (found from table)
    • $m$: molality
    • $i$: van’t Hoff factor
  • freezing point depression: $\Delta T_f = K_f mi$
    • $K_f$: freezing point depression constant (found from table)
    • $m$: molality
    • $i$: van’t Hoff factor
  • osmotic pressure: $\Pi = iMRT$
    • $\Pi$: osmotic pressure
    • $i$: van’t Hoff factor
    • $M$: molarity
    • $R$: gas constant
    • $T$: temperature
  • van’t Hoff factor (i): ratio of moles of particles in solution to moles of formula units that are dissolved; # of electrolytes